2028CASEYS-1.tif i
AIIen ScMeriiaker
From: Leslie Bancroft [ Bancroft @barkerlemar.com]
Sent: Monday, August 18, 2014 8:23 AM
To: Allen Schoemaker
Subject: Casey's Blair Water Sample Results
Attachments: Casey's Blair Water Sample Results.PDF
Al,
Please find attached water sample analysis for the Casey's in Blair, NE for your review. Please let us know if we are
cleared to pump water from the tanks or if you need any further information.
Thank you,
LESLIE BANCROFT I SERVICE COORDINATOR
BARKER LEMAR PETROLEUM SERVICES
515.256.8814 515.256.0152 [f] Jwww.barkerlemar.com
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'kfeystone
ME M a E a
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LABORATORIES, INC. �
August 14 2014
Leah Calvert
Barker Lemar Engineering Consultants
1801 Industrial Circle
West Des Moines, IA 50265
RE: LC Project
CASYS - Blair, NE
Enclosed are the results of analyses for samples received by the laboratory on 08/08/14 14:50. If you have any
questions concerning this report, please feel free to contact me at 1- 800 - 858 -5227.
ANALYTICAL REPORT FOR SAMPLES
Client Sample ID Laboratory ID Matrix Date Sampled Date Received
Diesel 1H40586 -01 Water 08/08/1410:00 08/08/1414:50
Super 1H40586 -02 Water 08/08/1410:02 08/08/1414:50
Unleaded 1H40586 -03 Water 08/08/1410:04 08/08/1414:50
Composite of Samples 1, 2, and 3 1H40586 -04 Water 08/08/14 10:00 08/08/14 14:50
The results in this report apply to the samples analyzed in accordance with the Chain -of- Custody record. This report must be reproduced in its entirety. Page 1 of 15
Phone 641 -792 -8451 600 East 17th Street South Fax 641 - 792 -7989
Newton, IA 50208
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1'kfeystone
':. M E:. M B E.... R
LABORATORIES, INC.
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Barker Lemar Engineering Consultants Project: LC Project Reported
1801 Industrial Circle Project Number: CASYS - Blair, NE 08/14/14 18:12
West Des Moines, IA 50265 Project Manager: Leah Calvert
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The results in this report apply to the samples analyzed in accordance with the Chain -of- Custody record. This report ntust be reproduced in its entirety. Page 2 of 15
Phone 641 - 792 -8451 600 East 17th Street South Fax 641 - 792 -7989
Newton, IA 50208
I Lfeystone
M E M B E`, R
LABORATORIES, INC.
Barker Lemar Engineering Consultants Project: LC Project
Reported
1801 Industrial Circle Project Number: CASYS - Blair, NE 08/14/14 18:12
West Des Moines, IA 50265 Project Manager: Leah Calvert
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The results in this report apply to the samples analyzed in accordance with the Chain -of- Custody record. This report must he reproduced to its entirety. Page 3 of 15
Phone 641- 792 -8451 600 East 17th Street South Fax 641- 792 -7989
Newton, IA 50208
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m E B E R
LABORATORIES, INC.
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Barker Lemar Engineering Consultants Project: LC Project Reported
1801 Industrial Circle Project Number: CASYS - Blair, NE p
08/14/14 18:12
West Des Moines, IA 50265 Project Manager: Leah Calvert
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The results in this report apply to the samples analyzed ha accordance with the Chain -of- Custody' record. This report must be reproduced in its entirety. Page 4 of) 5
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Phone 641 - 792 -8451 600 East 17th Street South Fax 641 - 792 -7989
Newton, 6A 50208
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I
I'Lfeystone
M E M B E R
LABORATORIES, INC.
Barker Lemar Engineering Consultants Project: LC Project
Reported
1801 Industrial Circle Project Number: CASYS - Blair, NE
08/14/14 18:12
West Des Moines, IA 50265 Project Manager: Leah Calvert
Diesel
1H40586 -01 (Water)
Date Sampled: 8/8/2014 IO:OO:OOAM
Reporting
Analyte Result Limit Units Dilution Batch Prepared Analyzed Method Notes
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Keystone Laboratories, Inc. - Newton
Determination of Conventional Chemistry Parameters
BOD (5 day) ND 8 mg/L 2 IXH0294 08/08/14 08/08/1415:00 SM 5210 B
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The results in this report apply to the samples analyzed in accordance with the Chain- of- Cusiody record. This repw7 must be reproduced in its entirety. page 5 or 1$
Phone 641 - 792 -8451 600 East 17th Street South Fax 641 -792 -7989
Newton, IA 50208
i
1'kfeystone
M E M B ,R
t
LABORATORIES, INC. j
Barker Lemar Engineering Consultants Project: LC Project
Reported �
1801 Industrial Circle Project Number: CASYS - Blair, NE
08/14/14 18:12
West Des Moines, IA 50265 Project Manager: Leah Calvert
Super
IH40586 -02 (Water)
Date Sampled:8 /8/2014 10:02:OOAM
Reporting
Analyte Result Limit Units Dilution Batch Prepared Analyzed Method Notes
Keystone Laboratories, Inc. - Newton
Determination of Conventional Chemistry Parameters
BOD (5 day) ND 8 mg/L 2 1XH0294 08/08/14 08/08/1415:00 SM 5210 B
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The results in this report apply to the sainples analyzed in accordance with the Chain- of- Cusiody record. This report must be reproduced in its entirety. Page 6 of 15
Phone 641 - 792 -8451 600 East 17th Street South Fax 641- 792 -7989
Newton, IA 50208
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I'Lfeystone
M E- M B E R
LABORATORIES, INC.
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Barker Lemar Engineering Consultants Project: LC Project
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1801 Industrial Circle Project Number: CASYS - Blair Reported
, NE 08/14/1 ed
West Des Moines, IA 50265 Project Manager: Leah Calvert
Unleaded
11140586 -03 (Water)
Date Sampled: 8/8/2014 10:04:OOAM
Reporting
Analyte Result Limit Units Dilution Batch Prepared Analyzed Method Notes
Keystone Laboratories, Inc. - Newton
Determination of Conventional Chemistry Parameters
BOD (5 day) ND 8 mg/L 2 1XH0294 08/08/14 08/08/14 15:00 SM 5210 B
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The results in this report apply to the samples analyzed in accordance with the Chain -of- Custody record. This report must he reproduced in its entirely. Page 7 of 15
Phone 641 - 792 -8451 600 East 17th Street South Fax 641- 792 -7989
Newton, IA 50208
i
i
%Lfeystone
M E M B E R
LABORATORIES, INC.
I
i
Barker Lemar Engineering Consultants Project: LC Project
Reported
1801 Industrial Circle Project Number: CASYS - Blair, NE 08/14/14 18:12
West Des Moines, IA 50265 Project Manager: Leah Calvert
Composite of Samples 1, 2, and 3
iH40586 -04 (Water)
Date Sampled:8 /8/2014 10:00:OOAM
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Reporting
Analyte Result Limit Units Dilution Batch Prepared Analyzed Method Notes j
Keystone Laboratories, Inc. - Newton
Determination of Extractable Petroleum Hydrocarbons
TEH, as gasoline ND 0.1 mg/L I 1XH0462 08/13/14 08/14/14 12:49 Iowa OA -2
TEH, as #2 diesel fuel 0.2 0.1 D -03, D -06
TEH, as waste oil 0.2 0.1 "
Total Extractable Hydrocarbons 0.4 0.1
Surrogate: Pentacosane 90.1% 50 -151
Determination of Conventional Chemistry Parameters
Solids, total suspended ND 4 mg/L 4 1XH0399 08/12/14 08/12/14 15:45 USGS j
I- 3765 -85
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Determination of Total Metals j
Silver, total ND 0.0040 mg/L 4 1XH0359 08/12/14 08/13/1418:59 EPA 6020A
Arsenic, total ND 0.0040
Barium, total 0.0166 0.0040
Cadmium, total ND 0.0008 "
Chromium, total ND 0.0080
Mercury, total ND 0.00050 1 1XH0366 08/12/14 08/12/1414:51 EPA 7470A
Lead, total ND 0.0040 4 1XH0359 08/12/14 08/13/1418:59 EPA 6020A
Selenium, total ND 0.0040 "
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The results in this repot/ apply to the samples analyzed in accordance with the Chain-of- Custody record. This repot/ must he reproduced in its enffrety. Page $ Of 1$
Phone 641 -792 -8451 600 East 17th Street South Fax 641- 792 -7989
Newton, IA 50208
i
I
I Lfeystone
' M E M e, E a
�l
LABORATORIES, INC.
Barker Lemar Engineering Consultants Project: LC Project
Reported
1801 Industrial Circle Project Number: CASYS - Blair, NE 08/14/14 18:12
West Des Moines, IA 50265 Project Manager: Leah Calvert
Determination of Extractable Petroleum Hydrocarbons - Quality Control
Keystone Laboratories, Inc. - Newton
Reporting Spike Source %REC RPD
Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes
Batch 1XH0462 - 3510C OA -2 Sep Fnl
Blank (1XH0462 -BLKl) P 08/13/14 Analyzed: 08/14/14
TEH, as gasoline ND 0.1 mg /L
TEH, as #2 diesel fuel ND 0.1 "
TEH, as waste oil ND 0.1 "
Total Extractable Hydrocarbons ND 0.1 "
Surrogate: Pentacosane 0.0438 0.0498000 87.9 50 -151
LCS (1XH - BS I) Pre pared: 08/13/14 Analyze 08/14/1
TEH, as #2 diesel fuel 5.98 0.1 mg/L 7.53800 79.4 57 -111
Surrogate: Pentacosane 0.0572 0.0498000 115 50 -151
LCS Dup (1XH0462 - BSDI) P repared: 08/13/1 Analyzed: 08/14
TEH, as #2 diesel fuel 5.63 0.1 - mg/L 7.53800 74.6 57 -111 6.17 30
Surrogate: Pentacosane 0.0559 0.0498000 112 50 -151
Reference (1XH0462 - SRMl) Prepared: 08/13/1 Analyzed: 08/14/14
TEH, as #2 diesel fuel 7.27 0.1 mg /L 7.53800 96.5 70 -130
Surrogate: Pentacosane 0.0585 0.0498000 117 50 -151
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The results in this report apply to the samples analyzed at accordance Wth the Chain -of- Custody record. This report must be reproduced in its entirety. Page 9 of 15
Phone 641 - 792 -8451 600 East 17th Street South Fax 641- 792 -7989
Newton, IA 50208
I Lfeystone } ., M E- M B E R �
LABORATORIES, INC.
Barker Lemar Engineering Consultants Project: LC Project
Reported
1801 Industrial Circle Project Number: CASYS - Blair, NE 08/14/14 18:12
West Des Moines, IA 50265 Project Manager: Leah Calvert
Determination of Conventional Chemistry Parameters - Quality Control
Keystone Laboratories, Inc. - Newton
Reporting Spike Source ° /uREC RPD
Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes
Batch 1XH0294 - General Prep Micro
Blank (1XH0294 -BLKI) Prep ared & Analyzed 08/ 08/14
BOD (5 day) ND 4 mg/L
Reference (1XH0294 - SRM1) Prepared & Analyzed: 08/08/14
BOD (5 day) 194 4 mg/L 198.000 98.0 84.6 -115.4
Batch IXH0399 - Wet Chem Preparation
Blank (1XH0399 -BLKI) Prepared & Analyzed: 08/12/14
Solids, total suspended ND I mg /L
LCS (1XH0399 - BSI) Pr epare d & Analyzed: 08/12
Solids, total suspended 13.2 1 mg/L 15.0000 88.0 64 - 121
Duplicate (1XH0399 - DUP1) Source 1H40455 - 02 Pre pared & Analyzed 08/1 2/14
Solids, total suspended ND 4 mg/L ND 19
The results in this report apply to the samples analyzed in accordance with the Chain -of- Custody record. This report must be reproduced in its entirety. Page 10 of 15
Phone 641 - 792 -8451 600 East 17th Street South Fax 641- 792 -7989
Newton, IA 50208
i
I
I
Ufeystone
a�
LABORATORIES, INC.
Barker Lemar Engineering Consultants Project: LC Project
Reported
1801 Industrial Circle Project Number: CASYS - Blair, NE 08/14/14 18:12
West Des Moines, IA 50265 Project Manager: Leah Calvert
Determination of Total Metals - Quality Control
Keystone Laboratories, Inc. - Newton
Reporting Spike Source ° /.REC RPD
Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes
Batch 1XH0359 - EPA 3010A Digestion (Water)
Blank (1XH03 -BLK1) Prepared: 08/12/14 Analy 08/13/14
Arsenic, total ND 0.0040 mg/L
Barium, total ND 0.0040 "
Cadmium, total ND 0.0008 "
Chromium, total ND 0.0080 "
Lead, total ND 0.0040 "
Selenium, total ND 0.0040 "
Silver, total ND 0.0040 "
LCS (1XH - BS1) Prepare 08/12/14 Analyzed: 08/13/14
Arsenic, total 0.0968 0.0040 mg /L 0.100000 96.8 80 -120
Barium, total 0.102 0.0040 0.100000 102 80 -120
Cadmium, total 0.101 0.0008 0.100000 101 80 -120
Chromium, total 0.0977 0.0080 0.100000 97.7 80 -120
Lead, total 0.0988 0.0040 0.100000 98.8 80 -120
Selenium, total 0.0878 0.0040 0.100000 87.8 80 -120
Silver, total 0.111 0.0040 0.100000 111 80 -120
Matrix Spike (1XH0359 - MS1) Source: 1H40586 - 04 Prepared: 08/12/14 Analyzed: 08/13/1
Arsenic, total 0.117 0.0040 mg/L 0.100000 0.0022 114 75 -125
Barium, total 0.211 0.0040 0.100000 0.0166 195 „ 75 -125 QM -07
Cadmium, total 0.103 0.0008 0.100000 ND 103 75 -125
Chromium, total 0.101 0.0080 0.100000 0.0063 95.0 75 -125
Lead, total 0.0985 0.0040 0.100000 ND 98.5 75 -125
Selenium, total 0.1015 0.0040 0.100000 0.0027 98.8 75 -125
Silver, total 0.114 0.0040 0.100000 0.00009 114 75 -125
Matrix Spike Dup (1XH0359 - MSD1) Source: 1H40586 - 04 Prepared: 08/12/14 Analyzed: 08/13/14
Arsenic, total 0.101 0.0040 mg/L 0.100000 0.0022 99.1 75 -125 14.0 20
Barium, total 0.212 0.0040 0.100000 0.0166 195 75 -125 0.155 20 QM -07
Cadmium, total 0.102 0.0008 0.100000 ND 102 75 -125 0.874 20
Chromium, total 0.0997 0.0080 0.100000 0.0063 93.3 75 -125 1.62 20
Lead, total 0.0977 0.0040 0.100000 ND 97.7 75 -125 0.740 20
Selenium, total 0.0912 0.0040 0.100000 0.0027 88.5 75 -125 10.7 20
Silver, total 0.111 0.0040 0.100000 0.00009 111 75 -125 2.65 20
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The results in this report apply to the samples analyzed in accordance with the Chain -of- Custody record. This report must he reproduced in its watrrety. Page 11 Of 1$
Phone 641- 792 -8451 600 East 17th Street South Fax 641 -792 -7989
Newton, (A 50208
I
L'feystone
r M E M B E .R
LABORATORIES, INC.
Barker Lemar Engineering Consultants Project: LC Project
Reported
1801 Industrial Circle Project Number: CASYS - Blair, NE
08/14/14 18:12
West Des Moines, IA 50265 Project Manager: Leah Calvert
Determination of Total Metals - Quality Control j
Keystone Laboratories, Inc. - Newton
Reporting Spike Source ° /uREC RPD
Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes
Batch 1XH0359 - EPA 3010A Digestion (Water)
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Post Spike (1XH0359 -PSI) Source: 1H40586 -04 Prepared: 08/12/14 Analyzed: 08/13/14
Arsenic, total 0.0838 mg/L 0.0800000 0,0022 102 80 -120
Barium, total 0.105 0.0800000 0.0163 111 80 -120
Cadmium, total 0.0865 0.0800000 0.00005 108 80 -120
Chromium, total 0.0858 0.0800000 0.0062 99.5 80 -120
Lead, total 0.0804 0.0800000 0.0001 100 80 -120
Selenium, total 0.0744 0.0800000 0.0026 89.8 80 -120
Silver, total 0.0850 0.0800000 0.00009 106 80 -120
Batch 1XH0366 - EPA 7470A Hg Water
Blank (1XH0366 - BLKI) Prepared & Analyzed: 08/1
Mercury, total ND 0.00050 mg/L
LCS (1XH0366 -BS1) Pr epared &Analyzed >08 /12/14
Mercury, total 0.00260 0.00050 mg/L 0.00250000 104 69 -125
Matrix Sp ike (I XH0366 -MS1) Source: 1H40586 -04 Prepared & Analyzed: 08/1
Mercury, total 0.00276 0.00050 mg/L 0.00250000 ND 110 60 -128
Matrix Spike Dup (1XH0366 -MSDI) Source: 1H40586 -04 Prepared & Analyzed: 08/12/14
Mercury total 0.00249 0.00050 mg/L 0.00250000 ND 99.6 60 -128 10.3 20
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The results in this report apply to the sampler analyzed in accordance with the Chain -of- Custody record. Nits report must he reproduced in its entirety. Page 12 of 15
Phone 641 - 792 -8451 600 East 17th Street South Fax 641- 792 -7989
Newton, IA 50208
I
I'Lfeystone
M E M B E R
LABORATORIES, INC.
Barker Lemar Engineering Consultants Project: LC Project
Reported
1801 Industrial Circle Project Number: CASYS - Blair, NE 08/14/14 18:12
West Des Moines, IA 50265 Project Manager: Leah Calvert
Certified Analyses Included in This Report
Method/Matrix Analvte Cortifiratinnc
EPA 6020A in Water
Arsenic, total NELAC,SIAIX,KS -NT
Barium, total NELAC,SIAIX,KS -NT
Cadmium, total NELAC,SIAIX,KS -NT
Chromium, total NELAC,SIAIX,KS -NT
Lead, total NELAC,SIAIX,KS -NT
Selenium, total NELAC,SIAIX,KS -NT
Silver, total NELAC,SIAIX,KS -NT
EPA 7470A in Water
Mercury, total KS- NT,NELAC,S IA 1 X
Iowa OA -2 in Water
Total Extractable Hydrocarbons SIA1X
SM 5210 B in Water
BOD (5 day) SIA1X
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USGS I- 3765 -85 in Water
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Solids, total suspended SIAIX,NELAC,KS -NT
Code Certifying Authority Certificate Number Expires
KS -KC Kansas Department of Health and Environment -KC E -10110 04/30/2015
KS -NT Kansas Department of Health and Environment E -10287 10/30/2014
MO -KC Missouri Department of Natural Resources 140 04/30/2014
NELAC New Jersey Department of Environmental Protection IA001 06/30/2015
SIA1X Iowa Department of Natural Resources 95 02/01/2014
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The results in this report apply to the samples analyzed in accordance with the Chain-of-Custody record. '!'his report must be reproduced in its entirety. Page 13 Of 15
Phone 641- 792 -8451 600 East 17th Street South Fax 641- 792 -7989
Newton, IA 50208
I,
(
'Lfeystone 0 1
'! M E M B E n
LABORATORIES, INC.
Barker Lemar Engineering Consultants Project: LC Project Reported
1801 Industrial Circle Project Number: CASYS - Blair, NE 08/14/14 18:12
West Des Moines, IA 50265 Project Manager: Leah Calvert
Notes and Definitions
QM -07 The spike recovery and /or RPD was outside acceptance limits for the MS and /or MSD. The batch was accepted based on acceptable
LCS recovery.
D -06 The sample chromatographic pattern does not resemble the fuel standard used for quantitation.
D -03 The result for this hydrocarbon is elevated due to the presence of single analyte peak(s) in the quantitation range.
DET Analyte DETECTED
ND Analyte NOT DETECTED at or above the reporting limit
NR Not Reported
dry Sample results reported on a dry weight basis
RPD Relative Percent Difference
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The results in this report apply to the samples analyzed in accordance nvith the Chain -of- Custody record. This report most be reproduced in its entirety. Page 14 of 15
Phone 641 - 792 -8451 600 East 17th Street South Fax 641 - 792 -7989
Newton, IA 50208
I Lfeystone
j
M E -.: M B E R
1
LABORATORIES, INC.
I
Barker Lemar Engineering Consultants Project: LC Project
Reported
1801 Industrial Circle Project Number: CASYS - Blair, NE 08/14/14 18:12
West Des Moines, IA 50265 Project Manager: Leah Calvert
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Sue Thompson
Project Manager II
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The results in this report apply to the samples analyzed in accordance with the Chain -of- Custody record. This report must be reproduced in its entirety. Page 15 of 15
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Phone 641 - 792 -8451 600 East 17th Street South Fax 641- 792 -7989
Newton, IA 50208
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